Degradation of Polymers
While the plastics industry searches for solutions to the problem of plastics waste, there is, surprisingly, a growing band of people trying to save plastics. The classic nightmare that we will all end up beneath a tide of plastics bottles and packaging is evaporating as plastics reveal that they are not the everlasting materials that we thought they were. Although the manufacturers of early ‘plastics’ such as horn buttons, Bois Durci paperweights or celluloid collars would be astonished to see how well many of their goods have survived, many other plastics have begun to show disturbing signs of instability. Every collection of plastics worldwide, from the Science Museum and Tate Gallery to the Comb & Plastics Museum in Oyonnax, has already lost or is losing unique and beautiful pieces through degradation.
AZoM - Metals, Ceramics, Polymer and Composites : Degradation of a celluloid Polymer
Figure 1. Degradation is clearly apparent from this 1930’s shoehorn made of celluloid.
Plastics, Not as Long-Lasting as Once Thought
The crucial fact is that plastics are organic and have been described as a time bomb ticking away since cellulose nitrate based plastics were invented around 130 years ago. It can of course be argued that manufacturers’ foremost intentions have never been to make beautiful objects for museums. However, museums have a duty to preserve their acquisitions. Two conferences on this subject have already been held in Britain during the first quarter of 1995. The tone of the second conference, organised by The National Museums of Scotland in Edinburgh in April, was fatalistic but determined.
Recognition of Polymer Degradation
It was not until the late 1980s that attention was paid to the fact that plastics artefacts had been physically changing, showing signs of acid vapour, tackiness, warping, embrittlement and crazing. Cellulose nitrate and cellulose acetate were particularly affected. By 1991 John Morgan of the Plastics Historical Society had collected enough data to write Conservation of Plastics -An Introduction, a joint PHS /Conservation Unit publication, and the Conservation Unit launched a survey to identify objects at risk with the aim of setting up a research programme. The survey included everything from radios and cables to textiles and sculptures.
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